Five things oak does

Flavour compounds

Oak staves contain vanillin (vanilla), lactones (coconut), guaiacol (smoke, clove), and furfural (almond, caramel). These compounds dissolve into wine during maturation. New oak imparts more than old; smaller barrels more than large.

Micro-oxygenation

Wood is porous. A tiny amount of oxygen passes through the staves into the wine over months. This softens harsh tannin by promoting polymerisation — tannin chains bind together and precipitate out, leaving the wine rounder.

Tannin extraction

Oak wood contains ellagitannins — a different type of tannin from grape-skin tannins. These dissolve into wine and contribute structure and texture. Oak tannins are generally smoother and less astringent than grape tannins.

Evaporation

About 2–3% of barrel contents evaporate annually through the wood (the "angel's share"). This concentrates the remaining wine — increasing flavour intensity, body and alcohol proportionally.

Reduction of acidity

Malolactic fermentation (MLF) often occurs during barrel ageing. This bacterial process converts sharp malic acid to softer lactic acid, reducing perceived acidity and adding a creamy, buttery texture, especially in Chardonnay.

Barrel size and toast level

A standard Bordeaux barrel (barrique) holds 225 litres. A Burgundy barrel (pièce) holds 228 litres. A large Slovenian oak cask (used in Barolo) holds 5,000–10,000 litres. The smaller the barrel relative to its wine volume, the more oak surface area contacts the wine — and the more flavour and micro-oxygenation it delivers. This is why small new-oak barriques have such a pronounced influence.

During cooperage, the inside of the barrel is toasted over an open flame. Light toast preserves more wood tannin and vanilla; medium toast balances flavour compounds and reduces harsh tannins; heavy toast adds smoke, coffee and caramel flavours. Most fine wine uses medium-toast barrels; heavily toasted barrels are common in bolder New World reds.

When to choose un-oaked

Un-oaked wines — fermented and aged in stainless steel, concrete or neutral large-format wood — preserve primary fruit character: the grape's own flavours of citrus, stone fruit or berry. This is why Chablis is unoaked (the mineral, saline character of the Kimmeridgian soil is the point), and why light aromatic whites like Riesling and Sauvignon Blanc rarely see oak. Oak would overwhelm their delicacy.

For more on how oak interacts with tannin, see the tannin glossary entry. For how it fits into the broader winemaking process, see the How wine is made guide.

Sources: WSET (winemaking and oak chemistry curricula), OIV (oenological practice standards), AWRI (oak and micro-oxygenation research), ACS Publications (vanillin and ellagitannin chemistry peer-reviewed research). Last updated: 2026-10-15. Corrections via the contact form.