Key phenolic compounds in the grape
Provide structure, astringency and ageing potential in red wine. At phenolic ripeness, skin tannins feel ripe and velvety rather than hard and grippy.
Seed tannins are harsh and green when unripe. A key indicator of phenolic ripeness is seed colour (brown = ripe; green = unripe) and a crunchy, bitter seed flavour.
Stem tannins can add freshness and spice when fully ripe (whole-cluster fermentation) or a green, stalky bitterness when underripe.
Pigments that give red wine its colour. Accumulate during véraison (colour change) and continue developing as the grape ripens.
UV-filtering antioxidants in the grape skin. Contribute to wine's antioxidant capacity and colour stability.
Sugar ripeness vs phenolic ripeness
Grapes accumulate sugars and develop phenolics at different rates. In warm climates and warm vintages, both tend to progress together, making harvest timing simpler. In cool climates — Burgundy, Bordeaux in cool years, the Loire, English vineyards — sugars may reach fermentable levels while seeds are still green and skins still taste harsh. This divergence is one reason cool climate reds present different winemaking challenges. Some producers add water (where legally permitted) or use chaptalization (adding sugar pre-fermentation) to adjust the sugar-phenol balance.
Phenolic ripeness and tannin texture
The textural effect of tannins on the palate — whether a wine feels silky, grippy, velvety or harsh — is directly related to phenolic ripeness at harvest. Ripe tannins are polymerised into longer chains that interact more gently with salivary proteins, producing a smooth, mouth-coating sensation. Unripe tannins are shorter-chain compounds that bind more aggressively with proteins, creating a drying, astringent sensation. This is why wines from hot, ripe vintages often feel rounder and more immediately approachable than wines from cool, challenging years. See tannin for a full treatment of how tannin structure affects wine texture.
Sources: AWRI (grape and wine phenolics research); WSET (Level 3 viticulture and harvest ripeness curricula); Académie Amorim (tannin chemistry references). Last updated: 2026-10-19. Corrections via the contact form.